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Organic Peroxide Tbpb CAS: 614 45 3 Liquid Tbpb 98% Basic Info
Model NO.:TBPB
Type:Pharmaceutical Intermediates
Appearance:Liquid
Quality:Industrial
Colour:White
CAS No:614-45-9
Mf:C11h14o3
Einecs No:202-049-5
Appearanced:Clear Liquid
Boiling Point:124
Melting Point:8
Cn-No:52076
Trademark:LEASTY
Transport Package:Standard Packaging Size
Specification:CE, SGS
Origin:Shanghai
HS Code:2929100000
Organic Peroxide Tbpb CAS: 614 45 3 Liquid Tbpb 98% Product Description
TBPB as low volatile, pale yellow transparent liquid, is a kind of esters, organic peroxides.Used as a polymerization (such as polystyrene, polyethylene, poly (acrylic acid) of medium temperature curing agent, initiator,unsaturated polyester and silicone rubber vulcanizing agent.
Specifications of TBPB:
Safety data |
Half-life data |
||
Thermal decomposition temperature |
60oC |
Activation energy |
33kcal/mole |
Flash point |
Open 65 oC Silent 19 oC |
10 hours Half-life temperature |
105oC |
SADT |
63oC |
1 hour half-life temperature |
125oC |
Tem |
55oC |
1 minute half-life temperature |
167oC |
UN-No |
3103 |
||
CN-No |
52076 |
||
Physical and chemical properties |
main quality indicators |
||
state |
liquid |
appearance |
Pale yellow transparent oily liquid |
proportion |
1.043 |
Content |
Min.98% |
Refractive index |
1.499 |
Chroma |
Max. 100 hazen |
Boiling point |
124oC |
Fe |
Max.0.0003% |
Melting point |
8oC |
||
Active oxygen content |
8.24% |
Solubleness of TBPB:
Soluble in alcohol, ester, ether, organic solvents.Does not dissolve in water.
1. Polymerization of styrene
TBPB can be used for the polymerization and copolymerization of styrene in the temperature
range of 100-140°C. During polymerization the temperature is increased in steps.
2. Polymerization of acrylates and methacrylates
TBPB can be used as initiator for the solution (co)polymerization of acrylates and
methcrylates in the temperatures range of 100-170°C, amongst others for the coatings.
TBPB can also be applied as an initiator for the bulk and suspension (co)polymerization of
acrylates and methcrylates.
3. Polymerization of ethylene
TBPB is an efficient initirtor for the ethylene polymerization under high pressure in both
autoclave and tubular processes.
To obtain a wide spectrum of polymerization temperatures, combinations with other peroxides
are applied in practice.
Depending on reaction conditions. TBPB is active in the temperature range of 220-270°C.
4. Other applications
TBPB can also be used for the (co)polymerization of acrylonitrile and vinyl acetate.
5. Crosslinking Peroxides
TBPB,is suitable for crosslinking of EPDM rubber compounds at ambient temperature within
some weeks.
Rubber compounds containing TBPB have moderate processing safety in combination with a
very high speed of cure.
6. Peroxides for Thermoset Resins
TBPB, tert-butyl peroxybenzoate, is an aromatic perester, which is used for the curing of
unsaturated polyester resins at elevated temperatures.
TBPB is preferred for the curing of UP resin based Hot Press
Moulding formulations (SMC, BMC, ZMC etc) in the temperature range of 120 - 170°C
Packaging & Shipping
20 kg, 25 kg PE barrels packaging10 ~ 30 oC storage in a cool ventilated place.
For the customer the demand is higher chroma, should be stored under 10 ~ 15 oC.